Bis(N-benzoyl-N-phenylhydroxylaminato-κ2 O,O′)dimethyltin(IV)
نویسندگان
چکیده
The Sn atom in the title compound, [Sn(CH(3))(2)(C(13)H(10)NO(2))(2)], has a highly distorted octa-hedral coordination with the equatorial plane made up of four O atoms from two N-benzoyl-N-phenyl-hydroxy-laminate ligands and the axial positions occupied by two methyl groups. The crystal structure is stabilized by van der Waals inter-actions.
منابع مشابه
(2,2′-Bipyridine-κ2 N,N′){[(3-methoxy-2-oxidobenzylidene-κO 2)hydrazono]methanolato-κ2 N 2,O}dimethyltin(IV)
In the crystal structure of the title compound, [Sn(CH(3))(2)(C(9)H(8)N(2)O(3))(C(10)H(8)N(2))], the Sn atom exhibits a penta-gonal bipyramidal coordination geometry defined by two C, three N and two O atoms. The bond distances for Sn-C, Sn-N and Sn-O are in the ranges 2.097 (3)-2.098 (3), 2.298 (2)-2.623 (2) and 2.157 (2)-2.266 (2) Å, respectively. The mol-ecular structure of the monomeric com...
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متن کامل(4-Methylbenzohydrazidato-κ2 N′,O)[2-(4-methylbenzoylhydrazinylidene-κ2 N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate
The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazono)propionate dianion. The octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds, generati...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011